Synthesis and characterization of acidic properties of Al-SBA-15 materials with varying Si/Al ratios

Al-SBA-15 of varying Si/Al ratios in the range 11.4–78.4 was synthesized using tri-block copolymer P123. The calcined materials were examined by XRD, pore size distribution, surface area, ²⁷Al NMR spectroscopy. The acidity and acid strength distribution were studied using microcalorimetric adsorption of NH₃. The acidic properties were also examined by cumene cracking reaction as a function of Si/Al ratios. Systematic variation of acidity and activity was observed as a function of Si/Al ratio. The initial heats of NH₃ adsorption correlated well with activity indicate that acid sites with ΔH > 100 kJ/mole is responsible for cumene cracking activity. Linear correlations were obtained with total acidity and cumene cracking activities. The tetrahedral aluminum was found to be responsible for the observed acidities and catalytic activities.     

Organometallic L-Alanine Cadmium Iodide Crystals for Optical Device Fabrication

Single crystals of L-alanine cadmium iodide (LACI) were grown by the slow evaporation technique at room temperature. A single-crystal X-ray diffraction (SXRD) model was used to evaluate the crystal structure of the as-grown LACI crystal. The energy dispersive X-ray (EDX) analysis and ultraviolet-visible-near infrared (UV-vis-NIR) transmittance studies were carried out, and the results reveal the presence of elements in the title compound. From the transmittance data, the optical bandgap as a function of photon energy was estimated, and the different optical constants were calculated. A fluorescence study was performed for the LACI crystal. Thermogravimetric and differential thermal analyses have also been studied to investigate the thermal property of the LACI crystal. The efficiency of the second harmonic generation (SHG) of the title crystal was investigated. The magnetic and electrical properties were estimated by the vibrating sample magnetometer (VSM) analysis and impedance study, respectively.     

Experimental study on conventional solar still integrated with inclined solar still under different water depth

This study primarily focuses on comparative experimental analysis on standalone conventional solar still (CSS), inclined solar still (ISS), and integrated conventional and inclined solar still (CSS‐ISS) for different parameters that affect the freshwater yield. For enhancing the freshwater yield only a few studies are available on still‐still integration. The present novel study provides a greater improvement in improving the freshwater yield by integrating ISS with CSS. This experimental work mainly concentrates on the importance of water depth (d _w) and mass flow rate of water ( m _w) in the solar still. Water depth inside the conventional still varied from 0.02 to 0.06 m whereas, water is constantly flown with a mass flow rate of 8.33 kg/hour in an ISS with baffles. The experimental result shows that the accumulated freshwater yield from CSS‐ISS, ISS, and CSS were 6.2, 5.04, and 4.24 kg, respectively. CSS‐ISS and ISS produced 46.23% and 18.87% higher productivity than the CSS. From the experimental investigation, it is also identified that the water temperature is significantly improved by 20% using integration as compared with CSS without integration under the same water depth of d _w = 0.02 m. The overall improvement in yield was higher in the case of CSS‐ISS. The deviations between experimental and theoretical values of yield from the conventional and modified solar still were in the range of ±7%.     

A comparison of stress intensity factors obtained through crack closure integral and other approaches using eXtended element-free Galerkin method

In this paper, a new approach for extracting stress intensity factors (SIFs) by the extended element-free Galerkin method, through a crack closure integral (CCI) scheme, is proposed. The CCI calculation is used in conjunction with a local smoothing technique to improve the accuracy of the computed SIFs in a number of case studies of linear elastic fracture mechanics. The cases involve problems of mixed-mode, curved crack and thermo-mechanical loading. The SIFs by CCI, displacement and stress methods are compared with those based on the M-integral technique reported in the literature. The proposed CCI method involves very simple relations, and still gives good accuracy. The convergence of the results is also examined.     

Fullerenes as Photocatalysts: Studies on Decomposition of Water and Oxalic Acid

The paper presents data on the photocatalytic decomposition of water and destruction of oxalic acid using the fullerene mixture as a photocatalyst. Based on the data obtained, mechanisms are proposed for the destruction of oxalic acid and splitting of water.     

A high-performance computing method for data allocation in distributed database systems

Enhancing the performance of the DDBs (Distributed Database system) can be done by speeding up the computation of the data allocation, leading to higher speed allocation decisions and resulting in smaller data redundancy and shorter processing time. This paper deals with an integrated method for grouping the distributed sites into clusters and customizing the database fragments allocation to the clusters and their sites. We design a high speed clustering and allocating method to determine which fragments would be allocated to which cluster and site so as to maintain data availability and a constant systemic reliability, and evaluate the performance achieved by this method and demonstrate its efficiency by means of tabular and graphical representation. We tested our method over different network sites and found it reduces the data transferred between the sites during the execution time, minimizes the communication cost needed for processing applications, and handles the database queries and meets their future needs.     

Quasi‐Continuous Wave Near‐Infrared Excitation of Upconversion Nanoparticles for Optogenetic Manipulation of C. elegans

Optogenetics is an emerging powerful tool to investigate workings of the nervous system. However, the use of low tissue penetrating visible light limits its therapeutic potential. Employing deep penetrating near‐infrared (NIR) light for optogenetics would be beneficial but it cannot be used directly. This issue can be tackled with upconversion nanoparticles (UCNs) acting as nanotransducers emitting at shorter wavelengths extending to the UV range upon NIR light excitation. Although attractive, implementation of such NIR‐optogenetics is hindered by the low UCN emission intensity that necessitates high NIR excitation intensities, resulting in overheating issues. A novel quasi‐continuous wave (quasi‐CW) excitation approach is developed that significantly enhances multiphoton emissions from UCNs, and for the first time NIR light‐triggered optogenetic manipulations are implemented in vitro and in C. elegans. The approach developed here enables the activation of channelrhodopsin‐2 with a significantly lower excitation power and UCN concentration along with negligible phototoxicity as seen with CW excitation, paving the way for therapeutic optogenetics.     

State-of-the-art nanoplatform-integrated MALDI-MS impacting resolutions in urinary proteomics

Urine proteomics has become a subject of interest, since it has led to a number of breakthroughs in disease diagnostics. Urine contains information not only from the kidney and the urinary tract but also from other organs, thus urinary proteome analysis allows for identification of biomarkers for both urogenital and systemic diseases. The following review gives a brief overview of the analytical techniques that have been in practice for urinary proteomics. MALDI-MS technique and its current application status in this area of clinical research have been discussed. The review comments on the challenges facing the conventional MALDI-MS technique and the upgradation of this technique with the introduction of nanotechnology. This review projects nano-based techniques such as nano-MALDI-MS, surface-assisted laser desorption/ionization, and nanostructure-initiator MS as the platforms that have the potential in trafficking MALDI-MS from the lab to the bedside.     

Resilience of super users’ mental models of enterprise-wide systems

Research on information system training has focused primarily on methods, while neglecting the effects of interruption intervals between training and system implementation. This empirical study examines the resilience of accurate mental models of an enterprise-wide system in a large health care facility. Accurate mental models were shown to withstand the passage of time and resulted in superior field performance following a crash conversion. Consistent with prior experimental research, certain types of learners were more likely to acquire these sounder mental models. In large organisations where the simultaneous training of users on a complex system is virtually impossible, scheduling is an important facet of the training paradigm. The main practical implications of this study involve the development of: (1) training programmes emphasising performance on far-transfer tasks, (2) training schedules designed to minimise knowledge erosion, and (3) criteria for selecting highly capable super users.